Chapter 17 : Carbonates, Sulfates, Phosphates, Tungstates, Molybdates, & Borates

Part.3 : PHOSPHATES

PHOSPHATES

ionic bond → anisodesmic

key structural element is presence of tetrahedral PO₄³- anionic groups, & phosphorus ions have +5 charge, so phosphate groups anisodesmic

Only few phosphate minerals likely to be encountered routinely, Apatite, monazite, xenotime, & Turquoise
Composition of Apatite
The principal compositional variation is in the relative amounts of OH, F, & Cl

Fluorapatite Ca₅(PO₄)₃F
Hydroxylapatire Ca₅(PO₄)₃OH
Chlorapatite Ca₅(PO₄)₃Cl

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